Superconductivity in efficient thermoelectric Cu₃Sb₀.₉₈Al₀.₀₂Se₄

الأصل · EN

Both superconductivity and thermoelectricity offer promising prospects for daily energy efficiency applications. The advancements of thermoelectric materials have led to the huge improvement of the thermoelectric figure of merit in the past decade. By applying pressure on a highly efficient thermoelectric material Cu₃Sb₀.₉₈Al₀.₀₂Se₄, we achieve dome-shape superconductivity developing at around 8.5 GPa but having a maximum critical temperature of 3.2 K at pressure of 12.7 GPa. The novel superconductor is realized through the first-order structural transformation from its initial phase to an orthorhombic one. The superconducting phase is determined in the ultimate formation of the Cu-Al-Sb-Se alloy.