المساق
arXiv 2012-08-30 DOI 10.1063/1.4763986 0 مشاهدة

Electrostatic interactions mediated by polarizable counterions: weak and strong coupling limits

Démery, Vincent · Dean, David S. · Podgornik, Rudolf

الأصل · EN

We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar dielectric slab geometry with charged boundaries. We investigate the density profiles and the disjoining pressure for both approximations. Comparison to the case of non-polarizable counterions shows that polarizability brings important differences in the counterion density distribution as well as the counterion mediated electrostatic interactions between charged dielectric interfaces.

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