Negative Impurity Magnetic Susceptibility and Heat Capacity in a Kondo Model with Narrow Peaks in the Local Density of Electron States

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Temperature dependencies of the impurity magnetic susceptibility, entropy, and heat capacity have been obtained by the method of numerical renormalization group and exact diagonalization for the Kondo model with peaks in the electron density of states near the Fermi energy (in particular, with logarithmic Van Hove singularities). It is shown that these quantities can be negative. A new effect has been predicted (which, in principle, can be observed experimentally), namely, the decrease in the magnetic susceptibility and heat capacity of a nonmagnetic sample upon the addition of magnetic impurities into it.