Ag colloids and arrays for plasmonic non-radiative energy transfer from quantum dots to a quantum well

الأصل · EN

Ag nanoparticles in the form of colloids and ordered arrays are used to demonstrate plasmon-mediated non-radiative energy transfer from quantum dots to quantum wells with varying top barrier thicknesses. Plasmon-mediated energy transfer efficiencies of up to 25% are observed with the Ag colloids. The distance dependence of the plasmon-mediated energy transfer is found to follow the same d⁻⁴ dependence as the direct quantum dot to quantum well energy transfer. There is also evidence for an increase in the characteristic distance of the interaction, thus indicating that it follows a Förster-like model with the Ag nanoparticle-quantum dot acting as an enhanced donor dipole. Ordered Ag nanoparticle arrays display plasmon-mediated energy transfer efficiencies up to 21%. To explore the tunability of the array system, two arrays with different geometries are presented. It is demonstrated that changing the geometry of the array allows a transition from overall quenching of the acceptor quantum well emission to enhancement, as well as control of the competition between the quantum dot donor quenching and energy transfer rates.