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arXiv 2005-09-15 DOI 10.1140/epje/e2005-00056-3 0 views

A van der Waals free energy in electrolytes revisited

Jancovici, B.

Original · EN

A system of three electrolytes separated by two parallel planes is considered. Each region is described by a dielectric constant and a Coulomb fluid in the Debye-Hückel regime. In their book Dispersion Forces, Mahanty and Ninham have given the van der Waals free energy of this system. We rederive this free energy by a different method, using linear response theory and the electrostatic Maxwell stress tensor for obtaining the dispersion force.

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