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arXiv 2012-09-05 DOI 10.1063/1.4794593 0 views

Slow dynamics in cylindrically confined colloidal suspensions

Saklayen, Nabiha · Hunter, Gary L. · Edmond, Kazem V. · Weeks, Eric R.

Original · EN

We study bidisperse colloidal suspensions confined within glass microcapillary tubes to model the glass transition in confined cylindrical geometries. We use high speed three-dimensional confocal microscopy to observe particle motions for a wide range of volume fractions and tube radii. Holding volume fraction constant, we find that particles move slower in thinner tubes. The tube walls induce a gradient in particle mobility: particles move substantially slower near the walls. This suggests that the confinement-induced glassiness may be due to an interfacial effect.

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