The one-dimensional Lennard-Jones system: collective fluctuations and breakdown of hydrodynamics

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The dynamical correlations of a model consisting of particles constrained on the line and interacting with a nearest--neighbour Lennard--Jones potential are computed by molecular--dynamics simulations. A drastic qualitative change of the spectral shape, from a phonon--like to a diffusive form, is observed upon reducing the particle density even ad moderate temperatures. The latter scenario is due to the spontaneus fragmentation of the crystal--like structure into an ensemble of "clusters" colliding among themselves. In both cases, the spectral linewidths do not follow the usual q² behaviour for small wavenumbers q, thus signalling a breakdown of linearized hydrodynamics. This anomaly is traced back by the presence of correlations due to the reduced dimensionality.