Giant Antiferromagnetically Coupled Moments in a Molecule-Based Magnet with Interpenetrating Lattices

الأصل · EN

The molecule-based magnet [Ru₂(O₂CMe)₄]₃[Cr(CN)₆] contains two weakly-coupled, interpenetrating sublattices in a body-centered cubic structure. Although the field-dependent magnetization indicates a metamagnetic transition from an antiferromagnet to a paramagnet, the hysteresis loop also exhibits a substantial magnetic remanance and coercive field uncharacteristic of a typical metamagnet. We demonstrate that this material behaves like two giant moments with a weak antiferromagnetic coupling and a large energy barrier between the orientations of each moment. Because the sublattice moments only weakly depend on field in the transition region, the magnetic correlation length can be directly estimated from the magnetization.