Comment on "Self-Averaging Stochastic Kohn-Sham Density-Functional Theory"

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In a recent Letter, Baer et al. present a stochastic method for Kohn-Sham density functional theory calculations. Their convergence criterion is the self-averaging total energy per electron, which requires a number of statistical samples that decreases with system size and enables a sublinear-scaling computational cost. However, the electron density, atomic forces, orbital energies, and many other physical quantities do not self-average, and this procedure causes their statistical errors to grow with system size. Convergence of non-self-averaging quantities requires that the number of samples be maintained with system size and is incompatible with a sublinear-scaling cost.