Ab initio calculations of oscillator strengths and lifetimes of low-lying states in Mo VI

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Relativistic coupled-cluster (RCC) calculations have been performed to estimate the electromagnetic forbidden transition probabilities, oscillator strengths and lifetimes of many low-lying states of five times ionized molybdenum (Mo VI). Contributions from the Breit interaction up to the first order of perturbation have been examined. Our results are in good agreement with the available other reported theoretical and experimental results. A long lifetime about 4.9854 s of the first excited state, 4d ²D₅/₂, has been predicted which can be a very useful criteria in the doping process of thin films. Correlations trends from various RCC terms to the transition amplitude calculations are discussed.