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arXiv 1999-05-27 DOI 10.1016/S0375-9601(99)00288-1 1 views

Optical Susceptibilities of Polymers: Current-Current versus Dipole-Dipole Correlation

Xu, Minzhong · Sun, Xin

Original · EN

The static current operator leads to definitional zero frequency divergence and unphysical results in studying nonlinear optical susceptibilities of polymers. A well-defined dipole-dipole correlation is superior to the complicated current-current correlation to solve this problem. As illustrative examples, optical susceptibilities under both SSH and TLM models of trans-(CH)ₓ are studied. New analytical results are obtained. The reasons of previous improper results are analyzed.

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