Cayley sum graphs and eigenvalues of (3,6)-fullerenes

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We determine the spectra of cubic plane graphs whose faces have sizes 3 and 6. Such graphs, "(3,6)-fullerenes", have been studied by chemists who are interested in their energy spectra. In particular we prove a conjecture of Fowler, which asserts that all their eigenvalues come in pairs of the form {λ,-λ} except for the four eigenvalues {3,-1,-1,-1}. We exhibit other families of graphs which are "spectrally nearly bipartite" in this sense. Our proof utilizes a geometric representation to recognize the algebraic structure of these graphs, which turn out to be examples of Cayley sum graphs.