Thermodynamic curvature for a two-parameter spin model with frustration
Ruppeiner, George · Bellucci, Stefano
الأصل · EN
Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated (1+3) Ising spin chain containing two microscopic parameters: a "stiff" K mediating the long-range interactions, and a "sloppy" J operating within local spin groups. K dominates the macroscopic behavior, and varying J has weak effect except in regions where J brings about transitions between phases through its conditioning of the local spin groups with which K interacts. We calculate the heat capacity Cₕ, the magnetic susceptibility χₜ, and the thermodynamic curvature R. For large |J/K|, we identify four magnetic phases: ferromagnetic, antiferromagnetic, and two ferrimagnetic ones, according to the signs of K and J. We argue that for characterizing these phases, the strongest picture is offered by the thermodynamic geometric invariant R, proportional to the correlation length ξ. This picture has correspondences to other cases, such as fluids.
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