Synthesis, Structure and Magnetic Properties of New Layered Iron-Oxychalcogenide Na2Fe2OSe2
He, J. B. · Wang, D. M. · Shi, H. L. · Yang, H. X. · Li, J. Q. · Chen, G. F.
Original · EN
A new layered iron-oxychalcogenide Na2Fe2OSe2 has been synthesized and structurally characterized by powder X-ray diffraction. The structure is formed by alternate stacking of the newly discovered [Fe2OSe2] blocks and double layers of Na. Conductivity study shows that Na2Fe2OSe2 is a semiconductor with activation energy of 0.26 eV. Magnetic susceptibility and heat capacity measurements reveal an antiferromagnetic phase transition occurs at TN=73 K. A broad maximum of magnetic susceptibility and a slow decay of the specific heat above TN, arises as a result of two-dimensional short-range spin correlation.
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