المساق
arXiv 2012-08-15 DOI 10.1021/ic4018135 0 مشاهدة

New layered fluorosulfide SrFBiS2

Lei, Hechang · Wang, Kefeng · Abeykoon, Milinda · Bozin, Emil S. · Petrovic, C.

الأصل · EN

We have synthesized a new layered BiS₂-based compound SrFBiS2. This compound has similar structure to BiS2. It is built up by stacking up SrF layers and NaCl-type BiS2 layers alternatively along the c axis. Electric transport measurement indicates that SrFBiS2 is a semiconductor. Thermal transport measurement shows that SrFBiS2 has a small thermal conductivity and large Seebeck coefficient. First principle calculations are in agreement with experimental results and show that SrFBiS2 is very similar to LaOBiS2 which becomes superconductor with F doping. Therefore, SrFBiS2 may be a parent compound of new superconductors.

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