ALMA Detection of Interstellar Methoxymethanol (CH₃OCH₂OH)
McGuire, Brett A. · Shingledecker, Christopher N. · Willis, Eric R. · Burkhardt, Andrew M. · El-Abd, Samer · Motiyenko, Roman A. · Brogan, Crystal L. · Hunter, Todd R. · Margulès, Laurent · Guillemin, Jean-Claude · Garrod, Robin T. · Herbst, Eric · Remijan, Anthony J.
الأصل · EN
We report the detection of interstellar methoxymethanol (CH₃OCH₂OH) in ALMA Bands 6 and 7 toward the MM1 core in the high-mass star-forming region NGC 6334I at 0.1" - 1" spatial resolution. A column density of 4(2) x 10¹⁸ cm⁻² at Tex = 200 K is derived toward MM1, 34 times less abundant than methanol (CH₃OH), and significantly higher than predicted by astrochemical models. Probable formation and destruction pathways are discussed, primarily through the reaction of the CH₃OH photodissociation products, the methoxy (CH₃O) and hydroxymethyl (CH₂OH) radicals. Finally, we comment on the implications of these mechanisms on gas-phase vs grain-surface routes operative in the region, and the possibility of electron-induced dissociation of CH₃OH rather than photodissociation.
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