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arXiv 2004-01-14 DOI 10.1103/PhysRevB.68.224420 0 views

On the effect of short-range magnetic ordering on electron energy-loss spectra in spinels

McComb, D. W. · Craven, A. J. · Chioncel, L. · Lichtenstein, A. I. · Docherty, F. T.

Original · EN

The energy-loss near-edge structure (ELNES) at the oxygen K edge in two AB₂O₄ spinels (A=Mg, B=Al,Cr) is reported. In MgAl₂O₄ the experimental data is successfully modelled within the LDA framework. In the case of MgCr₂O₄ spin-polarisation, in the form of antiferromagnetic ordering on the Cr sub-lattice, must be included despite the fact that the measurements were performed at approximately 30 times above Tₙ. A model in which dynamic short-range antiferromagnetic ordering is present at room temperature is proposed to explain the results of the experiments and calculations.

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