Structure-driven analog optical control in ion-pumped SrFeO₃₋δ thin-film devices

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Electrochromic devices (ECDs) offer a compelling route toward low-power, non-emissive optical modulators with nonvolatile states. However, their widespread implementation is hindered by limitations in operating voltage, switching speed, color tunability, and long-term stability. Mixed ionic-electronic conductors (MIECs) provide a promising alternative platform, enabling optical modulation through ion-driven redox and structural transformations. Oxygen-based MIECs offer enhanced durability, environmental robustness, and compatibility with oxide electronics and silicon photonics, yet remain largely underexplored for electrochromic and photonic applications. Here, we demonstrate structure-driven analog optical control in an ion-pumped SrFeO₃₋δ thin-film device by undergoing reversible oxygen-driven phase transitions between brownmillerite and perovskite structures. Phase transition is accompanied by pronounced changes in its electronic structure and optical constants. By harnessing these ion-induced structural transformations and integrating an optically passive Al₂O₃ interference layer, we achieve continuous and reversible modulation of optical transmittance and color. These results provide a general framework for ion-driven analog photonic and electrochromic devices and highlight the potential of oxygen-based MIECs for next-generation ionochromic systems compatible with silicon-based photonic platforms.