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arXiv 2000-09-14 0 views

Statistical mechanical derivation of the second law of thermodynamics

Tasaki, Hal

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In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a general equilibrium distribution. Therefore the second law is a logical necessity once we accept equilibrium statistical mechanics.

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