Surface Tension of an Ideal Dielectric - Electrolyte Boundary: Exactly Solvable Model
Šamaj, L.
Original · EN
The model under consideration is a semi-infinite two-dimensional two-component plasma (Coulomb gas), stable against bulk collapse for the dimensionless coupling constant β<2, in contact with a dielectric wall of dielectric constant =0. The model is mapped onto an integrable sine-Gordon theory with a ``free'' Neumann boundary condition. Using recent results on a reflection relationship between the boundary Liouville and sine-Gordon theories, an explicit expression is derived for the surface tension at a rectilinear dielectric -- Coulomb gas interface. This expression reproduces the Debye-Hückel β→ 0 limit and the exact result at the bulk collapse border, the free-fermion point β=2, where the surface tension keeps a finite value. The surface collapse, identified with the divergence of the surface tension, occurs at β=3.
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