Infrared properties of θ-type ET charge-transfer salts: θ-ET₂CsZn(SCN)₄ vs θ-ET₂RbZn(SCN)₄
Wang, N. L. · Feng, T. · Chen, Z. J. · Mori, H.
Original · EN
We performed polarized far-infrared reflectance measurements at different temperatures on θ-ET₂RbZn(SCN)₄ and θ-ET₂CsZn(SCN)₄, two typical charge-transfer salts in a series of isostructural θ-ET₂MM'(SCN)₄. The measurements revealed distinct differences in both electronic and vibronic spectra, which provides a clue towards understanding the different metal-insulator transitions of the two salts.
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