Role of structural fluctuations in the insertion into complex host matrices
Vakarin, E. V. · Badiali, J. P.
Original · EN
A coupling of structural and thermodynamic fluctuations in the course of various-type insertion processes is investigated within a combination of Gibbsian statistics and the information theory approach. It is shown that the coupling makes it possible to restore (at least partially) the information, inaccessible from experimental tests. This enables one to make physically reasonable predictions under limited information on the system.
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