High-temperature superconductivity and the characteristics of the electronic energy spectrum

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The possibility is indicated of applying the theory of superconductors with overlapping energy bands to describe the thermodynamic and electromagnetic properties of the high-temperature compounds La₂₋ₓ(Ba,Sr)ₓCuO₄ and YBa₂Ci₃O₇₋δ. The two-band model was used to obtain high values of Tc, two energy gaps 2Δ₁/Tc > 3.5 and 2Δ₂/Tc < 3.5, large negative values of d Tc/d V (V is the volume) in lanthanum ceramics, small values of the jump in the electron heat capacity at T=Tc, negative curvature of the upper critical magnetic field Hc₂ near the transition temperature, etc. Such behavior of the above quantities is observed experimentally. A description is also obtained of the decrease in Tc as the disordering of oxygen increases, and also as copper atoms are replaced by a nonmagnetic impurity (Al, Zn, etc.). The main mechanism responsible for this decrease is the interband scattering of electrons by impurities and by randomly distributed oxygen vacancies. A theory has been developed of multiband superconductors which takes into account the points of high symmetry in momentum space. On the basis of this theory one can explain the existence of a plateau in the dependence of Tc on δ for YBa₂Cu₃O₇₋δ, and also in the dependence of Tc on x for La₂₋ₓ(Ba,Sr)ₓCuO₄, that has been observed in a number of experiments. Moreover, this theory also explains the presence of two maxima in the dependence of Tc on pressure for Bi₂Sr₂CaCu₂O₈.